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The repository of the Institute of Nuclear Physics Polish Academy of Sciences collects, stores and shares documents that are the result of research work of the Institute's employees and doctoral students. Its purpose is to disseminate the scientific achievements of employees and promote scientific research conducted at the Institute. Access to bibliographic descriptions of deposited works and to the full texts of documents archived in the Repository of IFJ PAN is by default open to all users.

 

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Molar heat capacities of [NbIV{(μ-CN)4MnII(H2O)2]}2·4H2O]n molecular magnet
(Institute of Nuclear Physics Polish Academy of Sciences, 2025-03-28) Pełka, Robert; Miyazaki, Yuji; Nakazawa, Yasuhiro; Pinkowicz, Dawid
The deposited data include the molar heat capcities vs temperature of a molecular magnet [NbIV{(μ-CN)4MnII(H2O)2]}2·4H2O]n measured by the PPMS instrument in different magnetic fields of 0, 0.1, 0.2, 0.5, 1, 2, 3, 4, 5, 7, and 9 T. The data files are simple *.dat text files including two columns: the first column comprises temperature in kelvin (K), while the second column includes the corresponding molar heat capacity in J/K mol. The data were processed and analyzed and the results were used to prepare the manuscript entitled "Insight into magnetocaloric properties of Mn2Nb molecular magnet by relaxation calorimetry: A comprehensive case study" available at http://arxiv.org/abs/2503.21343. Zdeponowane dane zawierają molowe pojemności cieplne w funkcji temperatury magnetyka molekularnego [NbIV{(μ-CN)4MnII(H2O)2]}2·4H2O]n zmierzone na instrumencie PPMS w różnych polach magnetycznych 0, 0.1, 0.2, 0.5, 1, 2, 3, 4, 5, 7 i 9 T. Pliki z danymi mają prosty format pliku tekstowego z rozszerzeniem *.dat zawierający dwie kolumny: w pierwszej kolumnie znajduje się temperatura wyrażona w kelwinach (K), natomiast druga kolumna zawiera odpowiadającą tej temperaturze wartość molowej pojemności cieplnej w jednostkach J/K mol. Dane były opracowane i przeanalizowane a rezultaty posłużyły do przygotowania manuskryptu zatytułowanego "Insight into magnetocaloric properties of Mn2Nb molecular magnet by relaxation calorimetry: A comprehensive case study" dostępnego pod adresem http://arxiv.org/abs/2503.21343.
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Synthesis and characterization of SBA-15 silica containing cyclam inside pores for capturing iron chloride: Analysis of interactions between ferrous chloride and cyclam in a system with strongly dispersed functional groups on the SiO2 surface
(Microporous and Mesoporous Materials, 2024-07-04) Laskowski, Łukasz; Laskowska, Magdalena; Walcarius, Alain; Doskocz, Marek; Vila, Neus; Karczmarska, Agnieszka; Pawlik, Piotr; Goraus, Jerzy; Balin, Katarzyna; Dulski, Mateusz
The use of the spatial structure of mesoporous silica combined with organic molecules opens up a wide range of possibilities in the field of separation of single atoms and the precise creation of their environment. Materials obtained in this way can find applications as single-atom catalysts (SAC) and in environmental applications in ion and molecule trapping processes. An example of such a material is silica of the SBA-15 type functionalized with cyclam (1,4,8,11-tetraazacyclotetradecane) anchored inside the pores with propyl chains. In this work, we present such a material containing 5% functional groups, additionally activated with iron(II) chloride, which was chelated by cyclam anchored inside the pores of silica. The presented nanocomposite has been thoroughly tested for its assumed molecular structure and stability. We compared it to a material containing only cyclam. The obtained results showed the high efficiency of the silica matrix with cyclam in the separation of single FeCl2 molecules and the correct molecular structure of the obtained material. The nanocomposite containing chelated molecules with iron showed good stability, while the structure of the material with cyclam alone collapsed with time.
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Silica SBA-15 containing cyclam inside pores for capturing iron chloride
(Institute of Nuclear Physics Polish Academy of Sciences, 2025) Laskowska, Magdalena; Karczmarska, Agnieszka; Laskowski, Łukasz
The dataset collected as a result of the research project titled "Novel bioactive composite coatings based on silica nanostructures for biological and environmental applications" funded by the National Science Centre under the SONATA-17 competition, includes data from imaging by scanning electron microscopy (SEM) of the materials studied, energy dispersive X-ray spectrometry (EDS), and isothermal sorption of nitrogen. Data are published in Microporous and Mesoporous Materials 378 (2024) 113243. Zbiór danych, zgromadzonych w wyniku projektu badawczego pod tytułem "Nowe bioaktywne powłoki kompozytowe na bazie nanostruktur krzemionkowych dla zastosowań biologicznych i środowiskowych" finansowanego przez Narodowe Centrum Nauki w ramach konkursu SONATA-17, zawiera dane z obrazowania za pomocą elektronowej mikroskopii skaningowej SEM badanych materiałów, spektrometrii dyspersji energii promieniowania rentgenowskiego EDS i izotermicznej sorpcji azotu. Dane zostały opublikowane w Microporous and Mesoporous Materials 378 (2024) 113243.
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Mesoporous Silica-Carbon Composite Thin Films and Powders
(Institute of Nuclear Physics Polish Academy of Sciences, 2025) Laskowska, Magdalena; Karczmarska, Agnieszka
The dataset collected as a result of the research project titled "Novel bioactive composite coatings based on silica nanostructures for biological and environmental applications" funded by the National Science Centre under the SONATA-17 competition, includes data from Raman spectroscopy and isothermal sorption of nitrogen. Data are published in Materials 2024, 17, 6274. Zbiór danych, zgromadzonych w wyniku projektu badawczego pod tytułem "Nowe bioaktywne powłoki kompozytowe na bazie nanostruktur krzemionkowych dla zastosowań biologicznych i środowiskowych" finansowanego przez Narodowe Centrum Nauki w ramach konkursu SONATA-17, zawiera dane uzyskane za pomocą spektroskopii Ramana oraz izotermicznej sorpcji azotu. Dane zostały opublikowane w Materials 2024, 17, 6274.
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Molecular structure of copper phosphonate groups anchored inside SBA-15 silica channels analysis
(Institute of Nuclear Physics Polish Academy of Sciences, 2025) Laskowska, Magdalena; Doskocz, Marek
The dataset collected as a result of the research project titled "Novel bioactive composite coatings based on silica nanostructures for biological and environmental applications" funded by the National Science Centre under the SONATA-17 competition, includes the results obtained by Raman spectroscopy and numerical models used in the analysis of experimental data. Data are published in Applied Surface Science 669 (2024) 160425. Zbiór danych zgromadzonych w wyniku realizacji projektu badawczego pod tytułem "Nowe bioaktywne powłoki kompozytowe na bazie nanostruktur krzemionkowych dla zastosowań biologicznych i środowiskowych" finansowanego przez Narodowe Centrum Nauki w ramach konkursu SONATA-17 zawiera wyniki uzyskane za pomocą spekroskopii ramanoswkiej oraz modele numeryczne wykorzystane w analizie danych ekrpetymentalnych . Dane zostały opublikowane w Applied Surface Science 669 (2024) 160425.